Transformation and Distribution of Vanadium Phases in …
vanadium in fly ash was easier than that in stone coal. Keywords Stone coal ·Combustion fly ash ·Vanadium phases ·Sequential chemical extraction Introduction Stone coal is a kind of carbonaceous shale that contains vanadium. In China, the reserves of vanadium in stone coal are 1.18×l05 t in terms of V 2O 5, accounting for
A Comparative Study of Extracting Vanadium from Vanadium …
The vanadium extraction rate is generally low due to the low vanadium content in the vanadium slag [17]. 2 of 15 The direct vanadium extraction method, in which vanadium is extracted from ...
A Literature Review on Leaching and Recovery of Vanadium
The effect of roasting and leaching variables on vanadium extraction from boiler ash, such as roasting temperatures, NaCl dosages, roasting time, and solid:liquid ratios has been studied. The ...
Recovery of vanadium from heavy oil and Orimulsion fly ashes
The recovery of vanadium from the fly ashes of heavy oil and Orimulsion combustion was performed using a three-step process, which consisted of an acid leaching, oxidation and precipitation of the vanadium pentoxide, followed by washing of the precipitate. The overall yield of vanadium recovery was higher for the Orimulsion fly ash …
Vanadium recovery from oil fly ash by leaching, precipitation and
In order to reduce the environmental impact due to land disposal of oil fly ash from power plants and to valorize this waste material, the removal of vanadium was investigated using leaching processes (acidic and alkaline treatments), followed by a second step of metal recovery from leachates involving either solvent extraction or selective …
Thermodynamics of vanadium (V) solvent extraction by mixture of …
In the present study, the thermodynamics and mechanisms of vanadium extraction by a mixture of bis-2-ethylhexyl phosphoric acid (D2EHPA) and tri-n butyl phosphate (TBP) from sulfate medium were investigated. It was found that the maximum extraction percent of vanadium occurs at pH 1.8 under ambient conditions; this …
Metals | Free Full-Text | Extraction and Recovery of Metals from …
Roasting with soda ash is efficient and cheap for industrial applications and allows the extraction of molybdenum and vanadium after the leaching of the roasted catalyst in water. Under selected experimental conditions, i.e., roasting at 700 °C and adding 20 wt.% soda ash for 140 min, 70% molybdenum, and 80% vanadium were extracted …
Process development for recovery of vanadium and nickel from …
Although, the extraction of vanadium is selective (using ∼ 40% alkali at high temperature) and recovery is complete, another leaching process is required to recover the other metals. ... This study investigated the use of microwave-assisted leaching to recover the vanadium (V) and nickel (Ni) of fly ash collected from power plants. The fly ...
Modelling the dynamics of the industrial vanadium cycle using the
The vanadium content in iron-titanium ore, aluminium ore, uranium ore and ash from fossil fuel combustion has a potential of about 3.5 million ton vanadium per year at an extraction rate of 3.3%/year, if can be made technically feasible.
Phase transformation mechanism of boiler ash roasted with
The effect of roasting and leaching variables on vanadium extraction from boiler ash, such as roasting temperatures, NaCl dosages, roasting time, and …
Evaluation of Variables Determining Leaching Efficiency in Vanadium
The extraction process of vanadium from vanadiferous titanomagnetite ore deposited in Korea was investigated using a combination of alkali roasting and water-leaching processes. ... (Na 2 SO 4), and soda ash (Na 2 CO 3) were used as roasting additives. The highest extraction efficiency of vanadium was observed in the sulfate …
X-MOL
Optimization of vanadium(V) extraction by 2-ethyl-1-hexanol and the study of extraction reaction mechanism. Minerals Engineering ( IF 4.8 ) Pub Date: , ... Phase transformation mechanism of boiler ash roasted with sodium salt for vanadium extraction. Journal of Material Cycles and Waste Management (IF 3.1) Pub Date: , ...
Recovery of metals and other beneficial products from coal fly ash…
Shabtai J et al. (1993) Extraction of metal oxides from coal fly ash by microorganisms and a new microorganism useful therefor. US Patent No. 5231018 Shiroto Y et al. (2003) Production of high purity vanadium compound from vanadium-containing carbonaceous residues.
Extracting vanadium pentoxide from minerals and composite …
Vanadium extraction from fly ash. Fly ash specifically refers to the soot collected after burning fuel and coal, which is enriched with vanadium and can be used as a source of vanadium. Fly ash is generally treated by leaching with water, alkali, or acid solutions, where vanadium is separated from other impurities. ...
Separation of impurities aluminum and iron during pressure acid
A novel method of high-efficiency extraction of aluminum (Al) and lithium (Li) from coal fly ash (CFA) is proposed. The mixture of CFA and sodium pyrosulfate (Na 2 S 2 O 7) was subjected to mechanochemical activation, followed by the addition of sodium persulfate (Na 2 S 2 O 8) for pressure leaching.The results indicated that the leaching …
Extraction and separation of vanadium and nickel from fly ash …
Vanadium metal was selectively extracted (95%) with 0.1–0.2 M H 2 SO 3 at 323–363 K, with an ash/reagent ratio of 1/4 and extraction time of 45 min [15]. In a similar study, FA was heated at moderate temperatures (150 °C), a de-carburization and de-sulphurisation (pre-treatment) stage, and finally a smelting step in an electric-arc-furnace ...
A critical review on extraction and refining of vanadium metal
Vanadium products include three grades, vanadium slag and other vanadium extraction raw materials are primary vanadium products, vanadium oxides …
Extraction and separation of vanadium and nickel from fly ash …
Vanadium metal was selectively extracted (95%) with 0.1–0.2 M H 2 SO 3 at 323–363 K, with an ash/reagent ratio of 1/4 and extraction time of 45 min [15]. In a …
Vanadium Extraction from Fly Ash—Preliminary Study of
The vanadium component in the fly ash was successfully recovered by controlling the operating conditions of a continuous solvent extraction circuit which employed a series of mixer-settlers. View ...
Vanadium removal and recovery from bauxite residue leachates …
This work aims to test the efficiency of ion exchange resins for vanadium (V) removal and recovery from bauxite residue leachates at alkaline pH (11.5 and 13). As an environmental pollutant, removal of V from leachates may be an obligation of bauxite residue disposal areas (BRDA) long-term management requirements.
Vanadium Recovery from Oil Fly Ash by Carbon Removal and
For example, Vitolo et al. accomplished 83% vanadium recovery from a previously burned heavy oil fly ash using several stages, such as preliminary burning, …
A Critical Review of Extraction Methods for Vanadium from …
extraction methods that apply to vanadium production, particularly from petcoke, considering the environmental issues associated with each technique. Information on the characterization of US petcoke is also included to identify specific extraction …
Vanadium Recovery from Oil Fly Ash by Carbon Removal …
This research mainly focuses on the recovery of vanadium from oil fly ash by carbon removal and the roast-leach process. The oil fly ash contained about 85% …
THE EXTRACTION OF VANADIUM AND NICKEL FROM …
from Canadian Delayed coke fly ash. Flow sheet for the recovery of vanadium and nickel from fly ash. Vanadium extraction from Canadian Flexicoke. Nickel extraction from Canadian Flexicoke. Metal extractions from acid leaching of Canadian Flexicoke for 2 hours, as a function of temperature. Equilibrium diagrams for Fe-H2-FICI and Ni-H2-HCI.
Simultaneous recovery of vanadium and nickel from power plant fly-ash
Semantic Scholar extracted view of "Simultaneous recovery of vanadium and nickel from power plant fly-ash: optimization of parameters using response surface methodology." by E. Nazari et al. ... Salt roasting-basic leaching is the process which was applied to separate and extract vanadium from steel making … Expand. 35. 1 Excerpt;
Vanadium recovery by glycine precipitation | Environmental …
This paper reports a new process for vanadium recovery by precipitation with glycine in acidic medium. Glycine was an efficient precipitant for vanadium recovery. Nearly 95.75% vanadium was precipitated under the following reaction conditions: reaction temperature of 90 ℃, dosage of glycine at n (glycine)/n (V) = 6.0, reaction time of 60 min ...
Vanadium recovery from oil fly ash by leaching, precipitation and
Vanadium recovery from oil fly ash by leaching, precipitation and solvent extraction processes. 2007;27 (3):425-38. doi: 10.1016/j.wasman.2006.02.002. In order to reduce the environmental impact due to land disposal of oil fly ash from power plants and to valorize this waste material, the removal of vanadium was investigated using leaching ...
A Critical Review of Extraction Methods for Vanadium from Petcoke Ash
Recovery of vanadium from heavy oil and Orimulsion fly ashes. 10.1016/S0304-386X (00)00099-2. Sitnikova et al, 1990. Role of thermal oxidation in the process of vanadium extraction from refinery coke (solid oil residues). 10.1016/0031-6458 (90)90017-A. As this is a critical review, the authors should have reviewed existing …
Vanadium Recovery from Oil Fly Ash by Carbon Removal and
Vanadium Extraction by Carbon Burning and Roast-Leach Processes. Three different steps, such as carbon burning, salt roasting, and water leaching, were conducted to extract vanadium from the oil fly ash. First, a vanadium-enriched product could be obtained after carbon removal since the material contained a huge amount of …
Energizer Confirms Up to 82% Vanadium Extraction; Green Giant …
The pre-roasting of the representative samples was shown to greatly improve the vanadium extraction by soda ash leaching. Julie Lee Harrs, President and COO of Energizer, said, "This test program has confirmed an effective leach process that achieves high vanadium extraction, while at the same time, producing clean leach solutions very low in ...